{ "@context": "http://iiif.io/api/presentation/3/context.json", "id": "https://digital.middlesexcollege.edu/iiif/manifest/AA00002438/00001", "type": "Manifest", "label": { "none": [ "Click Chemistry via Coordination complexes using bis(bipyridyl) azido Complexes of Ruthenium (II)" ] }, "metadata": [ { "label": { "en": [ "Abstract" ] }, "value": { "none": [ "The generation of 1,4 and 1,5 disubstituted triazoles using \u201CClick Chemistry\u201D between terminal alkynes and alkyl and aryl azides catalyzed by Cu (I) is well established. However, a Ruthenium(II) ion coordinated to a triazole ring system has not yet been studied. The synthesis of a bis(azido) bis(bipyridyl) complex of Ru(II) is described here. A complete study of the electronic spectra of this complex confirms that Ru(II) is coordinated to two azido groups in the cis position. The impressive chemical stability of this Ruthenium azido complex makes it an ideal candidate to perform \u201CClick Chemistry\u201D with it on a variety of terminal and substituted alkynes. The reaction of the bisbipyridyl bis(azido) Ruthenium complex with terminal alkynes was investigated. The non activated terminal alkyne failed to react with the bis(azido)Ru(II) complex under the conditions in which the reaction was carried out." ] } }, { "label": { "en": [ "Publication Date" ] }, "value": { "none": [ "2013 December 17" ] } }, { "label": { "en": [ "Hierarchical Spatial" ] }, "value": { "none": [ "New Jersey -- Edison" ] } }, { "label": { "en": [ "Holding Location" ] }, "value": { "none": [ "Middlesex County College Institution" ] } }, { "label": { "en": [ "Permanent Link" ] }, "value": { "none": [ "http://middlesexcc.sobeklibrary.com/AA00002438/00001" ] } }, { "label": { "en": [ "Creator" ] }, "value": { "none": [ "Girish, Mekhala", "Ghosh, Phalguni", "Middlesex College, Department of Natural Sciences" ] } }, { "label": { "en": [ "Publisher" ] }, "value": { "none": [ "Middlesex College" ] } }, { "label": { "en": [ "Place of Publication" ] }, "value": { "none": [ "Edison, NJ" ] } }, { "label": { "en": [ "Type" ] }, "value": { "none": [ "Mixed Material" ] } }, { "label": { "en": [ "Source Institution" ] }, "value": { "none": [ "Middlesex County College Institution" ] } }, { "label": { "en": [ "Subjects / Keywords" ] }, "value": { "none": [ "College students -- poster presentations", "Student Works -- Natural Sciences -- poster presentations", "Chemistry", "Student works -- Natural Sciences -- academic theses", "Middlesex College (Edison, NJ) -- Student works", "Middlesex County College (Edison, NJ)" ] } }, { "label": { "en": [ "Temporal Coverage" ] }, "value": { "none": [ "Academic Year 2013-2014 ( 2013 - 2014 )" ] } }, { "label": { "en": [ "Title" ] }, "value": { "none": [ "Click Chemistry via Coordination complexes using bis(bipyridyl) azido Complexes of Ruthenium (II)" ] } }, { "label": { "en": [ "Series Title" ] }, "value": { "none": [ "Student Symposium 2013" ] } }, { "label": { "en": [ "Format" ] }, "value": { "none": [ "Mixed Material" ] } }, { "label": { "en": [ "Digital Resource Creation Date" ] }, "value": { "none": [ "6/23/2021" ] } } ], "service": [ { "@context": "http://iiif.io/api/search/2/context.json", "id": "https://digital.middlesexcollege.edu/iiif/manifest/AA00002438/00001/search", "type": "SearchService2", "profile": "http://iiif.io/api/search/2/search" } ], "seeAlso": [ { "id": "https://digital.middlesexcc.edu/content/AA/00/00/24/38/00001/AA00002438_00001.mets.xml", "type": "Dataset", "format": "application/mets\u002Bxml", "label": { "en": "METS" } }, { "id": "https://digital.middlesexcc.edu/content/AA/00/00/24/38/00001/marc.xml", "type": "Dataset", "format": "application/marcxml\u002Bxml", "label": { "en": "MARCXML" } } ], "items": [] }