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001        AA00002438_00001
005        20210623182552.0
006        m^^^^^o^^^^^^^^^^^
007        cr^^n^---ma^mp
008        210623n^^^^^^^^xx^^^^^^s^^^^^^^^^^^eng^d
245 00 |a Click Chemistry via Coordination complexes using bis(bipyridyl) azido Complexes of Ruthenium (II) |h [electronic resource].
260        |a Edison, NJ : |b Middlesex College, |c 2013 December 17.
490        |a Student Symposium 2013.
520 3    |a The generation of 1,4 and 1,5 disubstituted triazoles using “Click Chemistry” between terminal alkynes and alkyl and aryl azides catalyzed by Cu (I) is well established. However, a Ruthenium(II) ion coordinated to a triazole ring system has not yet been studied. The synthesis of a bis(azido) bis(bipyridyl) complex of Ru(II) is described here. A complete study of the electronic spectra of this complex confirms that Ru(II) is coordinated to two azido groups in the cis position. The impressive chemical stability of this Ruthenium azido complex makes it an ideal candidate to perform “Click Chemistry” with it on a variety of terminal and substituted alkynes. The reaction of the bisbipyridyl bis(azido) Ruthenium complex with terminal alkynes was investigated. The non activated terminal alkyne failed to react with the bis(azido)Ru(II) complex under the conditions in which the reaction was carried out.
533        |a Electronic reproduction. |c Middlesex County College Institution, |d 2021. |f (Middlesex County College) |n Mode of access: World Wide Web. |n System requirements: Internet connectivity; Web browser software.
535 1    |a Middlesex County College Institution.
648        |a 2013-2014 |y Academic Year 2013-2014.
650    0 |a College students -- poster presentations.
650    0 |a Student Works -- Natural Sciences -- poster presentations.
650    0 |a Chemistry.
650    0 |a Student works -- Natural Sciences -- academic theses.
650        |a Middlesex College (Edison, NJ) -- Student works.
650    0 |a Middlesex County College (Edison, NJ).
700 1    |a Girish, Mekhala, |e author, primary.
700 1    |a Ghosh, Phalguni, |e advisor.
700        |a Middlesex College, Department of Natural Sciences. |4 spn
830    0 |a Middlesex County College.
830    0 |a Student Symposium.
830    0 |a Student Works.
852        |a MCC |c Student Symposium
856 40 |u http://middlesexcc.sobeklibrary.com/AA00002438/00001 |y Electronic Resource
992 04 |a https:/digital.middlesexcc.edu/content/AA/00/00/24/38/00001/Research Thesis-Mekhala Girish -12-17-2013thm.jpg
997        |a Student Symposium


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